## Abstract Reduction of 2‐phenyl‐ and 2‐methyl‐__exo__‐3,4‐dichlorobicyclo[3.2.1]oct‐2‐enes with lithium aluminium hydride (LAH) or tributyltin hydride (TBTH) gave __endo__‐2‐phenyl‐3‐chlorobicyclo[3.2.1]oct‐3‐ene, 2‐phenyl‐3‐chlorobicyclo[3.2.1]oct‐2‐ene and their methyl analogues. The action of
Reaction of tributyltin hydride with 1,3,5-trinitrobenzene in the presence of tetraalkylammonium halides
✍ Scribed by M. P. Egorov; G. A. Artamkina; I. P. Beletskaya; O. A. Reutov
- Book ID
- 112441951
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 58 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1573-9171
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Dichloroindium hydride (Cl 2 InH), which was generated in situ by transmetallation between tributyltin hydride and indium trichloride, acted as a novel radical initiator for the reduction of organic halides with tributyltin hydride. The reaction was revealed to proceed through a radical process unde
When 1,2,3-selenadiazoles were treated with an excess amount of olefins in the presence of a catalytic amount of Bu3SnH and AIBN, the addition of a vinyl radical, which was generated in situ by the denitrogenation of 1,2,3-selenadiazoles, to the carbon-carbon double bond followed by intramolecular c
## Abstract The structure of the reaction product from 1,3,5‐trinitrobenzene and an excess (i.e. at least four moles) of diazomethane, as found many years ago by __Heinke__, is shown to be a seven‐membered ring‐compound condensed with two cyclopropane rings and with one pyrazoline ring (VII). If 1,