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Reaction of the carbonyls of group VI metals with benzonitrile and ω-cyanoalkylbenzenes

✍ Scribed by A. N. Nesmeyanov; V. S. Kaganovich; V. V. Krivykh; M. I. Rybinskaya

Book ID
112437350
Publisher
Springer
Year
1977
Tongue
English
Weight
437 KB
Volume
26
Category
Article
ISSN
1573-9171

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Octahedral metal carbonyls. : XXXVII. th
Octahedral metal carbonyls. : XXXVII. the kinetics and mechanism of reactions of amines with the group VI-B metal carbonyls
✍ J.E. Pardue; G.R. Dobson 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo