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Reaction of superacid HGeCl3with aromatic compounds. 8. Formation of long-lived carbocations stabilized by the GeCl3anion in the reaction with 1,3-dialkoxybenzenes; crystal structure of 1,1,3,5-tetrakis(trichlorogermyl)-3-ethoxycyclohexane

✍ Scribed by S. P. Kolesnikov; S. L. Povarov; A. I. Lutsenko; D. S. Yufit; Yu. T. Struchkov; O. M. Nefedov


Book ID
112448521
Publisher
Springer
Year
1990
Tongue
English
Weight
400 KB
Volume
39
Category
Article
ISSN
1573-9171

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## Abstract The thermal conversion of 1‐phenyl‐1‐buten‐3‐yne (1) into the cycloisomerization products naphthalene (2), azulene (3), and 1‐methylene‐1__H__‐indene (4) has been studied at temperatures between 550 and 1000Β°C, a reaction time of approximately 0.3 s at 13 Torr (FVP) and at low partial p