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Formation of a stable arenonium ion in the reaction of a superacid, HGeCl3, with 1,3,5-trimethoxybenzene

โœ Scribed by S. P. Kolesnikov; S. L. Povarov; A. I. Lutsenko; O. M. Nefedov


Book ID
112449745
Publisher
Springer
Year
1988
Tongue
English
Weight
124 KB
Volume
37
Category
Article
ISSN
1573-9171

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The formation of C3H3 (propynyl) radical
โœ Carlos E. Canosa-Mas; Mark Ellis; H. Monty Frey; Robin Walsh ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 350 KB

Results obtained from the photolysis of ketene with acetylene strongly support the formation of C,H, radicals in the title reaction. Stationary state studies are interpreted in terms of the reaction C,H: 5 C,H, + H with a rate constant (log8 s '1 which is compared to RRKM predictions. In pulsed lase