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Reaction of sulfuryl chloride with P-trimethylsilyl-C-tert-butyl-C-trimethylsilyloxymethylenephosphine

✍ Scribed by A. S. Ionkin; N. V. Nikolaeva; B. A. Arbuzov


Book ID
112562051
Publisher
Springer
Year
1990
Tongue
English
Weight
48 KB
Volume
39
Category
Article
ISSN
1573-9171

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Alkylation of C~ in tetrahydrofuran with tert-butyl chloride and lithium gives a variety of products. Adducts of general formula C~oH,(t-Bu)qO~(thf)~ (where t-Bu is the ten-butyl group and thf the tetrahydrofuryl group (C4H70)) have been detected by mass spectrometry, with n -< 8, q + y -< 18 and x