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Alkylation of C60. Reaction between C60 anions and tert-butyl chloride and mass spectrometry analysis

✍ Scribed by S. Bourcier; P. Chaurand; C. Ciot; S. Della-Negra; C. Fabre; V. Greugny; L. Marx; A. Rassat; A. Rousseau

Book ID: 104307524
Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 997 KB
Volume: 156
Category: Article
ISSN: 0168-1176
DOI: 10.1016/s0168-1176(96)04414-x

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✦ Synopsis

Alkylation of C~ in tetrahydrofuran with tert-butyl chloride and lithium gives a variety of products. Adducts of general formula C~oH,(t-Bu)qO~(thf)~ (where t-Bu is the ten-butyl group and thf the tetrahydrofuryl group (C4H70)) have been detected by mass spectrometry, with n -< 8, q + y -< 18 and x = 0, 1, 2 depending on experimental conditions. IR and NMR spectra of products confirm these assignments.

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