Reaction of Substituted 1,3,2-Dioxaborolanes with Acetonitrile
β Scribed by V.V. Kuznetsov; Yu.E. Brusilovskii; A.V. Mazepa
- Book ID
- 110313060
- Publisher
- Springer US
- Year
- 2001
- Tongue
- English
- Weight
- 120 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0009-3122
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π SIMILAR VOLUMES
Reaction of Substituted 1,3,2-Dioxaborinanes with Acetonitrile. -Reaction of substituted 1,3,2-dioxaborinanes (I) with acetonitrile in the presence of sulfuric acid results in the formation of 1,3-oxazines (III). A possible reaction mechanism is discussed.
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## Abstract The mass spectra of a series of 2β__p__βsubstituted phenylβ1,3,2βdioxaborolanes have been examined and compared with the mass spectrum of 2βphenylβ1,3,2βdioxaborolane. Formation of the substituted ion [C~7~H~6~X]^+^ by electron impact induced rearrangement has been found to be influence