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Reaction of silyl- and germylmercury compounds with potassium cyanide initiated by crown ethers

✍ Scribed by O. A. Kruglaya; B. A. Gostevskii; N. S. Vyazankin


Book ID
112437382
Publisher
Springer
Year
1977
Tongue
English
Weight
80 KB
Volume
26
Category
Article
ISSN
1573-9171

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As a consequence of the hydrophobic effect, the reaction between silyl enol ethers and aldehydes are shown to proceed without a catalyst in aqueous solution and neutral conditions providing crossed-aldol products with a 2Y~ selectivity, as under pressure, that is the reverse in comparison with the a