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New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride

✍ Scribed by Mukaiyama, Teruaki; Banno, Kazuo; Narasaka, Koichi

Book ID
120304503
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
710 KB
Volume
96
Category
Article
ISSN
0002-7863

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✍ AndreΒ΄ Lubineau; Elsa Meyer πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 359 KB

As a consequence of the hydrophobic effect, the reaction between silyl enol ethers and aldehydes are shown to proceed without a catalyst in aqueous solution and neutral conditions providing crossed-aldol products with a 2Y~ selectivity, as under pressure, that is the reverse in comparison with the a