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Reaction of saturated ketones with a trivalent uranium complex. Isolation and characterization of the alcoholate and enolate products

✍ Scribed by Raymond Adam; Claude Villiers; Michel Ephritikhine

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
166 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis

The ufanimn (III) complex Cp$J(THF) (Cp = I') -CsH5. THF = ~trahydfof~) reacted With saturpted ketoae~ RCOCH2R' to give equimolar mixtmes of the compounds Cp3U-OCHR(CH2R? andCp$_J4CR(=CHR?.

πŸ“œ SIMILAR VOLUMES

Reaction of a triazolinedione with simpl
Reaction of a triazolinedione with simple alkenes. Isolation and characterization of hydration products
✍ Zois Syrgiannis; Fotios Koutsianopoulos; Kenneth W. Muir; Yiannis Elemes πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 182 KB

## a b s t r a c t The reaction of N-phenyltriazolinedione with three simple alkyl-substituted alkenes in water/alcohol or water/acetone solution was found to give a mixture of the corresponding ene and water addition products. The new hydration products were characterized by spectroscopy, and in