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Reaction of a Vanadium(III) Amide with H2: Isolation and Characterization of a Polynuclear Mixed-Valence Polyhydrido–Nitrido Complex

✍ Scribed by Pietro Berno; Prof. Dr. Sandro Gambarotta


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
416 KB
Volume
34
Category
Article
ISSN
0044-8249

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Isolation and Characterization of a Porp
✍ Volz, Heinrich ;Müller, Wihelm 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 530 KB

## Abstract The isolation at −78°C and characterization of the novel crystalline reactive porphinatomanganese(IV) complex Mn‐(TDCPP)(OCl)~2~ (5) is described. 5 is compared with the porphinatomanganese(IV) complexes Mn(TDCPP)(C~6~H~5~IOCl)~2~ (2), Mn(TDCPP)(C~6~F~5~10C1)CI (3) and Mn(TDCPP)(OCH~3~)