✦ LIBER ✦
Isolation and Characterization of a Porphinatomanganese(IV) Complex from the Reaction of Dichloro Monoxide with 5,10,15,20-Tetrakis-(2,6-dichloropheny)porphinatomanganese(III) Chloride [Mn(EDCPP)CI]
✍ Scribed by Volz, Heinrich ;Müller, Wihelm
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 530 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2940
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✦ Synopsis
Abstract
The isolation at −78°C and characterization of the novel crystalline reactive porphinatomanganese(IV) complex Mn‐(TDCPP)(OCl)~2~ (5) is described. 5 is compared with the porphinatomanganese(IV) complexes Mn(TDCPP)(C~6~H~5~IOCl)~2~ (2), Mn(TDCPP)(C~6~F~5~10C1)CI (3) and Mn(TDCPP)(OCH~3~)~2~, (4). The stoichiometric reaction of 5 with triphenylphosphane yields 2.5 equivalents of triphenylphosphane oxide and 1.0 equivalent of Mn(TDCPP)Cl (1). Complex 5 epoxidizes stilbene, and oxygenates and chlorinates cyclohexane.