Reaction of PuO2 with molten MgCl2
โ Scribed by Donald A. Wenz; Irving Johnson
- Book ID
- 107768381
- Publisher
- Elsevier Science
- Year
- 1968
- Weight
- 145 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0020-1650
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Refractive indices of molten binary MgCl,-NaC1 and hlgCl2 -KC1 mixtures have been measured by the goniometer mcthod with visible Ii&t at nine wavelen\_pths. from which the electronic polarizabilities were estimated using the Clausius-Xiossotti equation.
The Rnman active phonon frequencies have been assigned in crystalline magnesium chloride and sic found consistent with that expected for the @d space group. Residual lattice bvlds rue obzrved in the meI!, just Aovs the melting point of MgClz, which strongly suggests it is structurally similar to the
A molecular dynamics comput;ltion on 3. model of KzhIgC1~ wherein the ionic interactions involve only central forces is reported. The predominant structure is B very well defined trigowl M&l; ion cluster. The Raman spectrum is discussed in terms of the potential of average force.