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Polarization phenomenon in molten MgCl2-KCl and MgCl2-NaCl

✍ Scribed by Yasuhiko Iwadate; Junji Tominaga; Kazuo Igarashi; Junichi Mochinaga

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
400 KB
Volume
110
Category
Article
ISSN
0009-2614

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✦ Synopsis

Refractive indices of molten binary MgCl,-NaC1 and hlgCl2 -KC1 mixtures have been measured by the goniometer mcthod with visible Ii&t at nine wavelen_pths. from which the electronic polarizabilities were estimated using the Clausius-Xiossotti equation.

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A molecular dynamics comput;ltion on 3. model of KzhIgC1~ wherein the ionic interactions involve only central forces is reported. The predominant structure is B very well defined trigowl M&l; ion cluster. The Raman spectrum is discussed in terms of the potential of average force.

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The Rnman active phonon frequencies have been assigned in crystalline magnesium chloride and sic found consistent with that expected for the @d space group. Residual lattice bvlds rue obzrved in the meI!, just Aovs the melting point of MgClz, which strongly suggests it is structurally similar to the