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Reaction of photochemically generated hot hydrogen atoms with but-2-ene and but-1-ene

✍ Scribed by K.H. Al-Niami; K.A. Holbrook; G.A. Oldershaw


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
675 KB
Volume
42
Category
Article
ISSN
1010-6030

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✍ Kisma Al-Niami; Kenneth A. Holbrook; Geoffrey A. Oldershaw πŸ“‚ Article πŸ“… 1988 πŸ› John Wiley and Sons 🌐 English βš– 491 KB

Highly excited 2-butyl radicals have been generated by addition of hot hydrogen atoms to but-2-ene. Atoms of initial energy 130 k J mol-' and 161 kJ mol-' were produced by photolysis of HzS. Rates of decomposition of the highly excited 2-butyl radicals were monitored by analysis of stabilization and