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Reaction of phenylphosphine with p-quinones

✍ Scribed by A. N. Pudovik; G. V. Romanov; V. M. Pozhidaev

Book ID: 112442060
Publisher: Springer
Year: 1978
Tongue: English
Weight: 225 KB
Volume: 27
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00946898

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The reaction ofp-quinone I with ylides 2a and 2b afforded the corresponding phosphonium salts $a,b, p-quinone-dimethanides 4a,b(Z) and 5a,b(E); substituted phenols 7a,b(Zand E) and coumatin-derivative 11 (only with 2a). The reaction of 1 with ylide 2c gave, besides 4¢, 5c and 8¢, hydroquinone[l]eycl