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Reaction of p-quinones with thioamides

โœ Scribed by Horak, V.; Manning, W. B.

Book ID
121408627
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
570 KB
Volume
44
Category
Article
ISSN
0022-3263

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The reaction ofp-quinone I with ylides 2a and 2b afforded the corresponding phosphonium salts $a,b, p-quinone-dimethanides 4a,b(Z) and 5a,b(E); substituted phenols 7a,b(Zand E) and coumatin-derivative 11 (only with 2a). The reaction of 1 with ylide 2c gave, besides 4ยข, 5c and 8ยข, hydroquinone[l]eycl