Reaction of Phenoxy Radicals with Methyl Radicals in the Gaseous Phase
โ Scribed by MULCAHY, M. F. R.; WILLIAMS, D. J.
- Book ID
- 109630386
- Publisher
- Nature Publishing Group
- Year
- 1963
- Tongue
- English
- Weight
- 213 KB
- Volume
- 199
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/199761a0
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๐ SIMILAR VOLUMES
The kinetics of reactions involving halogen atom abstraction from haloalkanes by methyl radicals have been studied in the gas phase. Arrhenius parameters for halogen atom transfer were determined relative to those for methyl radical combination: (2) ,,A2(L/rnol . s) E,(kcal/mol) CFC1, CF,CCl, CF,C
## Abstract The reaction of hydrogen atoms with diazomethane was used as a source of methyl radicals to study the reaction of oxygen atoms with methyl radicals. This investigation verifies directly the earlier results that formaldehyde is a major product and that the rate constant is greater than 3