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Reaction of oxiranes with lithium: deoxygenation leading to olefins

✍ Scribed by K.N. Gurudutt; B. Ravindranath

Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 122 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83943-5

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✦ Synopsis

Mono-, di-, tri-and tetra-substituted epoxide8 undergo facile deoxyge. nation yielding olefine when treated with lithium in tetrabydrofuran. Aliphatic epoxidee yield olefins with the same stereochemistry as the parent compound.

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