✦ LIBER ✦

Deoxygenation of oxiran compounds to olefins by [Fe4S4(SC6H5)4]2− in the presence of NaBH4

✍ Scribed by Takashi Itoh; Tetsuo Nagano; Mitsuo Sato; Masaaki Hirobe

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 148 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93901-2

No coin nor oath required. For personal study only.

✦ Synopsis

The dianion complex [Fe4S4(SC6Hs)4] 2-caused deoxygenation reaction of oxiran compounds to olefins in the presence of NaBH4. The reduced form [Fe4S4(SR)4] 3-was suggested as an active reductant in this reaction.

📜 SIMILAR VOLUMES

EPR and endor studies of paramagnetic ir

EPR and endor studies of paramagnetic iron-sulfur clusters in single crystals of the [Net4]2 [Fe6S4 (SC6H4-o-OH)4] model compound.

✍ L. Le Pape; G. Rius; B. Lamotte 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 76 KB

Catalytic Reduction of Acetylene by the

Catalytic Reduction of Acetylene by the Reduced Species of [Fe4S4L4]2− (L = SCH2CH2OH, SPh), [Mo2Fe6S8(SC2H5)3(SCH2CH2−OH)6]3− and [Mo2Fe6S8(SPh)9]3−

✍ Koji Tanaka; Makoto Honjo; Toshio Tanaka 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 784 KB

On the presence of the S4z-term in Fe(HC

On the presence of the S4z-term in Fe(HCOO)2 · 2H2O

✍ Izuru Kimura; Toshihiro Idogaki 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 180 KB

Photooxygenation of 5-aryl-2,4-diaminopy

Photooxygenation of 5-aryl-2,4-diaminopyrimidines leading to 4-amino-1,3,5-triazin-2-yl ketones and, in the presence of sodium borohydride, to 5,6-dihyro-4(3H)-pyrimidinones

✍ Thomas Oppenländer; Karl-Heniz Pfoertner; Peter Schönholzer 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 354 KB 👁 1 views

Metal Clusters as Ligands: Substitution

Metal Clusters as Ligands: Substitution of Fe ions in Fe/Mo/S Clusters by Thiophilic CuI Ions To Give Clusters with [Cu4Mo2Fe2S8]4+ and [Cu5Mo3Fe4S11]6+ Cores

✍ Markos Koutmos; Dimitri Coucouvanis 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 189 KB 👁 2 views

Metal Clusters as Ligands: Substitution of Fe ions in Fe/Mo/S Clusters by Thiophilic Cu I Ions To Give Clusters with [Cu 4 Mo 2 Fe 2 S 8 ] 4+ and [Cu 5 Mo 3 Fe 4 S 11 ] 6+ Cores

Metal Clusters as Ligands: Substitution

Metal Clusters as Ligands: Substitution of Fe ions in Fe/Mo/S Clusters by Thiophilic CuI Ions To Give Clusters with [Cu4Mo2Fe2S8]4+ and [Cu5Mo3Fe4S11]6+ Cores

✍ Markos Koutmos; Dimitri Coucouvanis 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 2 views