## Abstract The relativeβrate method has been used to determine the rate coefficients for the reactions of OH radicals with three C~5~ biogenic alcohols, 2βmethylβ3βbutenβ2βol (__k__~1~), 3βmethylβ3βbutenβ1βol (__k__~2~), and 3βmethylβ2βbutenβ1βol (__k__~3~), in the gas phase. OH radicals were prod
Reaction of OH Radicals with Acetone: Determination of the Branching Ratio for the Abstraction Pathway at 298 K and 1 Torr
β Scribed by Estelle Turpin; Christa Fittschen; Alexandre Tomas; Pascal Devolder
- Book ID
- 111545691
- Publisher
- Springer Netherlands
- Year
- 2003
- Tongue
- English
- Weight
- 116 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0167-7764
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π SIMILAR VOLUMES
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The rate constants for the reaction of OH radicals with a series of 1 chloroalkanes were measured at 295 K and at a total pressure of 1 atm. The rate constants were obtained by using the absolute technique of pulse radiolysis combined with kinetic UV-spectroscopy. The results are discussed in terms
The rate constant for the reaction of the hydroxyl radical with l,l, 1-trichloroacetaldehyde has been determined at 298 f. 2 K. Rate data were obtained at atmospheric pressure by a relative rate method. The rate constant was also measured at lower pressures (l-3.4 Torr) using the discharge flow tech
## Abstract Relative rate techniques were used to study the kinetics of the reaction of OH radicals with acetylene at 296 K in 25β8000 Torr of air, N~2~/O~2~, or O~2~ diluent. Results obtained at total pressures of 25β750 Torr were in good agreement with the literature data. At pressures >3000 Torr
Rate constants for the reactions of OH radicals with CH2-CHN02, CH2-CH-CH,NOZ and c-CaHsNOz have been determined at 298?2 K and a total pressure of 1 atm. Rate data for the reaction of OH radicals with CH2-CHZ, CH2=CH-CH3 and C-C&~ were also obtained for comparison purposes. The OH rate data for all