Reaction of nortricyclene with deuteriotrifluoroacetic acid. Evidence for the formation of edge-protonated cyclopropane intermediate
β Scribed by Kwang-Ting Liu
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 206 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The cluster [W~3~S~4~H~3~(dmpe)~3~]^+^ (1) (dmpe=1,2βbis(dimethylphosphino)ethane) reacts with HX (X=Cl, Br) to form the corresponding [W~3~S~4~X~3~(dmpe)~3~]^+^ (2) complexes, but no reaction is observed when 1 is treated with an excess of halide salts. Kinetic studies indicate that th