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Reaction of epoxides with phosphine selenides and trifluoroacetic acid. Evidence for the formation of episelenides

✍ Scribed by T.H. Chan; J.R. Finkenbine


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
200 KB
Volume
15
Category
Article
ISSN
0040-4039

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The rate constant for the gas-phase reaction of the hydroxyl radical with trifluoroacetic acid has been determined over the temperature range 283-323 K using a relative rate technique. The results provide a value of k( OH+CF,C(O)OH) = 2.O~lO-\*~exp(-l46~500/T)cm~molecule~'s-'basedonk(OH+C~H,)=7.8~lO

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