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Reaction of “Non-Symmetrical” 1,2,4-Trithiolanes with [(phosphane)Pt0(η2-nbe)] Complexes

✍ Scribed by Dr. Thomas Weisheit; Dr. Antje Kriltz; Dr. Helmar Görls; Prof. Dr. Grzegorz Mlostoń; Prof. Dr. Wolfgang Imhof; Prof. Dr. Wolfgang Weigand


Book ID
112006542
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
835 KB
Volume
7
Category
Article
ISSN
1861-4728

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Reactions of 1,2,4-Trithiolane and Its 4
✍ Holm Petzold; Thomas Weisheit; Silvio Bräutigam; Helmar Görls; Grzegorz Mloston; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 301 KB

## Abstract Reactions of 1,2,4‐trithiolanes with Pt^0^ complexes often proceed via an oxidative addition of the Pt^0^ complex fragment into the S–S bond and subsequent extrusion of a thioketone molecule by ring contraction. The six‐membered intermediate **5a**, formed in the course of the reaction