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Reaction of Negatively-Charged Clusters of Carbon Dioxide with CH 3 I: Formation of Novel Molecular Anion CH 3 CO 2 I -

✍ Scribed by Tsukuda, Tatsuya; Saeki, Morihisa; Iwata, Suehiro; Nagata, Takashi


Book ID
126029061
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
260 KB
Volume
101
Category
Article
ISSN
1089-5639

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Formation of [(CO2)nCH3I]βˆ’ anions in the
✍ Tatsuya Tsukuda; Morihisa Saeki; Takashi Nagata πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 403 KB

The reactions of negatively charged clusters of carbon dioxide, (CO2) ~, (N> 3), with CH3I were used to form [(CO2),CH3I]-. The observed product distribution showed a distinct bimodal behavior; the mass spectrum of the product anions consisted of [(CO2)nCH3I]-with n = 1-3 and n > 7, while those with