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Novel negatively charged cyanocuprate(I) host [Cu4(CN)7]3−built of tetrahedral Cu(I) coordination centers: Crystal structure of [{NH2(CH2CH2)2NCH2CH2NH2}2H][Cu4(CN)7]

✍ Scribed by Hidetaka Yuge; Toschitake Iwamoto

Publisher
Springer Netherlands
Year
1996
Tongue
English
Weight
423 KB
Volume
26
Category
Article
ISSN
0923-0750

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Investigations of the Copper Bromide–Eth
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✍ Robert P. Hammond; Douglas J. Chesnut; Jon A. Zubieta 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 429 KB

The hydrothermal reactions of CuBr 2 , CuBr, and ethylenediamine have resulted in the synthesis of two new compounds. [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 2 Br 4 }] has a two-dimensional sheet structure while [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 5 Br 7 }] crystallizes as a three-dimensional network. Bot