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Reaction of Naphtho- and Benzimidazolequinones with Enamines. Synthesis of Condensed Benzofurans and Indoles.

✍ Scribed by V. M. Lyubchanskaya; L. M. Alekseeva; S. A. Savina; V. G. Granik


Publisher
John Wiley and Sons
Year
2003
Weight
95 KB
Volume
34
Category
Article
ISSN
0931-7597

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✍ Kyoji Tsuchikama; Yu-ki Hashimoto; Kohei Endo; Takanori Shibata 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

## Abstract A directed cyclization‐dehydration cascade of α‐aryloxy ketones and α‐arylamino ketones was efficiently catalyzed by a cationic iridium‐BINAP complex, which afforded various types of 4‐substituted benzofurans and indoles in high yields with complete regioselectivity. The newly developed