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Reaction of Molecular Oxygen with a PdII– Hydride To Produce a PdII–Hydroperoxide: Acid Catalysis and Implications for Pd-Catalyzed Aerobic Oxidation Reactions

✍ Scribed by Michael M. Konnick; Bhavesh A. Gandhi; Ilia A. Guzei; Shannon S. Stahl

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
109 KB
Volume
45
Category
Article
ISSN
0044-8249

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Reaction of Molecular Oxygen with a PdII
Reaction of Molecular Oxygen with a PdII– Hydride To Produce a PdII–Hydroperoxide: Acid Catalysis and Implications for Pd-Catalyzed Aerobic Oxidation Reactions
✍ Michael M. Konnick; Bhavesh A. Gandhi; Ilia A. Guzei; Shannon S. Stahl 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 109 KB

Palladium-catalyzed reactions are among the most versatile methods for the selective aerobic oxidation of organic molecules. [1] These reactions are generally thought to proceed by a two-stage "oxidase" pathway that consists of Pd IImediated oxidation of the organic substrate followed by