Reaction of Molecular Oxygen with a PdII– Hydride To Produce a PdII–Hydroperoxide: Acid Catalysis and Implications for Pd-Catalyzed Aerobic Oxidation Reactions

✍ Scribed by Michael M. Konnick; Bhavesh A. Gandhi; Ilia A. Guzei; Shannon S. Stahl

• Publisher: John Wiley and Sons
• Year: 2006
• Tongue: English
• Weight: 109 KB
• Volume: 118
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/ange.200600532

✦ Synopsis

Palladium-catalyzed reactions are among the most versatile methods for the selective aerobic oxidation of organic molecules. [1] These reactions are generally thought to proceed by a two-stage "oxidase" pathway that consists of Pd IImediated oxidation of the organic substrate followed by