Reaction of Metastable Ar*( 3 P 2 ) and Kr*( 3 P 2 ) Atoms with Water Vapor: Excitation Functions for Electronic Quenching Collisions †
✍ Scribed by Mueller, Don R.; Krenos, John
- Book ID
- 120545628
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 98 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0022-3654
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The reactions of the lowest metast&bIe states of Ar, Rr and Xe with XeF2 were studied in a Bowing after$ow appamtus; XeF emission (from D \*111,2 and B 'C\* states) was observed in all cases. me toti rate constants (cm3 molecde-r S-I) for XeF\* formation were determined as 75 X l@' -Xe(3P2); 64 X lo
The violet emission spectrum (B\* Z-X' C) of the CN radical observed by the collision of HCN with metastable AI(~P, ?) atoms was analyzed. The effective rotational temperature of the CN(B2C) radical, 3s estimated from a band e&elope analysis, is about 2000°K. The disrributions of the excess energy t