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Reaction of malondialdehyde with guanine nucleosides: formation of adducts containing oxadiazabicyclononene residues in the base-pairing region

✍ Scribed by Marnett, Lawrence J.; Basu, Ashis K.; O'Hara, Shawn M.; Weller, Paul E.; Rahman, A. F. M. Maqsudur.; Oliver, John P.

Book ID: 111957865
Publisher: American Chemical Society
Year: 1986
Tongue: English
Weight: 434 KB
Volume: 108
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00266a065

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The treatment of guanine nucleosides and nucleotides with excess acetaldehyde in pH 8.0 phosphate buffer containing a basic amino acid such as arginine and lysine resulted in the smooth and selective formation of the corresponding cyclic 1,N 2 -propano adducts even under mild conditions.