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Reaction of lithium N,N-dialkylamide enolates with trialkylchlorosilanes

โœ Scribed by Woodbury, Richard P.; Rathke, Michael W.


Book ID
121716842
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
514 KB
Volume
43
Category
Article
ISSN
0022-3263

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Lithium diisopropylamide undergoes an addition reaction to the methyleneamino moiety of the title Schiffs bases substituted with a cyano group at the ortho or parn position of the aniline, but mediates tautomerization of the unsubstituted and metasubstituted derivatives into secondary enamines. Onl