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Reaction of isoxazoles and isoxazolium salts with organometallic reagents. Synthesis of dihydroisoxazoles

✍ Scribed by Albertola, Angel; Antol�n, Luis Fernando; Gonz�lez, Ana; Laguna, Miguel Angel; Pulido, Francisco Jos�

Book ID
111869264
Publisher
Royal Society of Chemistry
Year
1988
Weight
485 KB
Volume
4
Category
Article
ISSN
1472-7781

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✍ Purificación Cuadrado; Ana M. González-Nogal; Senén Martínez 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 827 KB

2-Pyrazolin-4-oximes have been synthesized by reaction of 4-nitroso-and 4nitropyrazoles with complex metal hydrides and organometallic reagents. Furthermore, 4nitropyrazolium tetrafluoroborates are reactive substrates towards organolithium and Grignard compounds leading to new and highly substituted