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Reaction of organometallic reagents with triethoxyacetonitrile. A new and short synthesis of α-ketoesters.

✍ Scribed by Georges P. Axiotis

No coin nor oath required. For personal study only.

✦ Synopsis

Grignard reagents react with triethoxyacetonitrile to give esters, while organolithium reagents provide cc-ketoesters in excellent yields.

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