Reaction of Hydrazonoyl Chlorides to Trimethylsilyl Homoallyl Ethers.
โ Scribed by Paolo Del Buttero; Giorgio Molteni; Sara Mondini; Alessandro Ponti
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 23 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb
suumlary: Trimethylsilyl chloride-sodium iodide has been used for the mild removal Of methoxyethoxymethyl ethers.
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