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Reaction of fluorosulfuryl isocyanate with group IIB metal fluorides [1]

✍ Scribed by R.E. Noftle; J.W. Green; S.K. Yarbro

Book ID: 104150712
Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 358 KB
Volume: 7
Category: Article
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)83998-6

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✦ Synopsis

Fluorosulfuryl isocyanate has been found to react with HgF2 and CdF2 in CH3CN solution to form the fluoroformylfluorosulfurylimide salts, Hg[N(S02F)C(0)F]2.X CH3CN (X = 1,2) and Cd[N(S02F)C(0)F-J2.2 CH3CN. The reaction with CdF 2 was incomplete, and no detectable reaction occurred with ZnF 2' HgCN(S02F)C(0)F]2 reacted with Cd2 to produce mainly COF2, FS02NCL2, and HgCC2. With CF3C(O)CG, the products CF3C(O)F, FS02NC0, and, possibly, Hg[N(S02F)C(0)F]CL were formed.

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