Reaction of [Et 4 N] 2 [Te{Cr(CO) 5 } n ] ( n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations
โ Scribed by Shieh, Minghuey; Ho, Li-Fang; Chen, Pei-Chi; Hsu, Miao-Hsing; Chen, Hui-Lung; Guo, Yu-Wen; Pan, Yi-Wen; Lin, Yi-Chun
- Book ID
- 127157537
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 835 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0276-7333
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## Me3P Me3P PMe, 1 2 3 stereoisomers which display hydride/PMe, cis-and hydride/CO trans-configurations. The syntheses of 2 and 3 were recently reported [5], and 1 was obtained in high yield by reduction of [ReCl(CO),(PMe,),] with Na in THF and subsequent acidification with H,O. Out of the seri
To assess the viability of 1,4diphosphabutadiyne (PCCP, 2 a) as a target for synthesis, we have investigated C 2 P 2 isomers 2, the end-on complexes [Cr(CO) 5 PCCP] (3) and [(CO) 5 Cr-(PCCP)Cr(CO) 5 ] (4), as well as their side-on analogues 6 and 7, respectively, using nonlocal density functional th