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Carbonylchromium Monotelluride Complexes [Et 4 N] 2 [Te{Cr(CO) 5 } n ] ( n = 2, 3): Two Important Intermediates

✍ Scribed by Shieh, Minghuey; Ho, Li-Fang; Guo, Yu-Wen; Lin, Shu-Fen; Lin, Yi-Chun; Peng, Shie-Ming; Liu, Yi-Hung


Book ID
126121459
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
162 KB
Volume
22
Category
Article
ISSN
0276-7333

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Insertion Reactions of [ReH(CO)5–n(PMe3)
✍ Daniel Nietlispach; Dario Veghini; Heinz Berke πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 German βš– 853 KB

## Me3P Me3P PMe, 1 2 3 stereoisomers which display hydride/PMe, cis-and hydride/CO trans-configurations. The syntheses of 2 and 3 were recently reported [5], and 1 was obtained in high yield by reduction of [ReCl(CO),(PMe,),] with Na in THF and subsequent acidification with H,O. Out of the seri