Reaction of enolate anions with lactones
β Scribed by Angelina J. Duggan; Michael A. Adams; Paul J. Brynes; Jerrold Meinwald
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 241 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
In the course of our studies directed towards the synthesis of pederawide &gradation product of pederin (g)4, we had occasion to explore the chemistry
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## Abstract Nitronate anions derived from primary and secondary nitroalβkanes undergo crossβcoupling reactions with diethyl alkylmalonate anions in alcohol/DMF solution when treated with silver nitrate. A catalytic amount of chloride ions is necessary to promote selective reaction.