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Reactions of organic anions, 173. Oxidative cross-coupling of enolates with nitronate anions promoted by chloride anions

✍ Scribed by Wróbel, Zbigniew ;M??kosza, Mieczysław

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 354 KB
Volume: 1990
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1990199001118

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✦ Synopsis

Abstract

Nitronate anions derived from primary and secondary nitroal‐kanes undergo cross‐coupling reactions with diethyl alkylmalonate anions in alcohol/DMF solution when treated with silver nitrate. A catalytic amount of chloride ions is necessary to promote selective reaction.

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