Reaction of dimethylsilylene with allylic methyl sulfides
β Scribed by Chihi, Abdelkrim.; Weber, William P.
- Book ID
- 127303125
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 403 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The aluminum-chloride catalyzed reaction of allyllc sulfides with methyl propiolate resulted ln the clean formatlon of novel 1 1 adducts via ionic [3 33 sigmatropic rearrangements. Pencyclic reactlons of organosulfur compounds have become increasingly important as a general synthetic method for the
## Abstract An efficient and mild reaction for introducing an allylic moiety and an alkylthioβ or alkylselenoβgroup onto the Ξ±βcarbon of Ξ²βdicarbonyl compounds in one step by tandem transylidation and [2,3]βsigmatropic rearrangement is described.