Reaction of Dimethyldichlorosilane with Hexamethyldisiloxane as a Source of Dimethylsilanone. A Route to Linear and Cyclic Polydimethylsiloxanes
β Scribed by M. G. Voronkov; M. V. Romanova; E. I. Dubinskaya
- Book ID
- 111608297
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 31 KB
- Volume
- 73
- Category
- Article
- ISSN
- 1070-3632
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π SIMILAR VOLUMES
Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce
## Abstract Diastereoselective synthesis of diethyl Zβ1βalkenylphosphonates from easily available diethyl thiocyanatomethylphosphonate and aromatic aldehydes has been developed. Olefination of the aldehydes occurs under mild conditions and affords the title compounds with moderate yields. A plausib