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Reaction of dimethyldichloro silane and dichloroanhydride of methylphosphonic acid with ethylamine

โœ Scribed by K. A. Andrianov; T. V. Vasil'eva'; A. A. Minaeva

Book ID
112419250
Publisher
Springer
Year
1963
Tongue
English
Weight
221 KB
Volume
12
Category
Article
ISSN
1573-9171

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The reaction of tris(trimethylsilyl)sila
The reaction of tris(trimethylsilyl)silane with acid chlorides
โœ M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 268 KB

Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb