The reaction of tris(trimethylsilyl)sila
โ
M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi
๐
Article
๐
1992
๐
Elsevier Science
๐
French
โ 268 KB
Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb