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Reaction of dimesitylsilylene in a cryogenic oxygen matrix. IR spectroscopic observation of a silylene-oxygen adduct

✍ Scribed by Akasaka, Takeshi.; Nagase, Shigeru.; Yabe, Akira.; Ando, Wataru.

Book ID
126322656
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
418 KB
Volume
110
Category
Article
ISSN
0002-7863

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Theoretical study of a silylene-oxygen a
Theoretical study of a silylene-oxygen adduct. Is a silanone oxide structure (H2SiOO) kinetically stable in the singlet state?
✍ Shigeru Nagase; Takako Kudo; Takeshi Akasaka; Wataru Ando πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 539 KB

In an attempt to reinforce our recent experiments on silylene-oxygen adducts, the structure and kinetic stability of silanone oxide (H2SiOO) in the singlet state have been investigated at several levels of theory. It is found that &none oxide has a nonplanar, pyramidal structure and undergoes rapid