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Low-temperature EPR study of the reaction of the 2,2,6,6-tetramethylpiperidyl radical with molecular oxygen. Direct spectroscopic observation of an aminylperoxyl radical

✍ Scribed by Göttinger, Heidi A.; Zubarev, Valentin E.; Brede, Ortwin


Book ID
121245775
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
99 KB
Volume
11
Category
Article
ISSN
1472-779X

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Kinetics of the reactions of 2,4,6-tri-t
✍ A. P. Griva; E. T. Denisov 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 318 KB

Reactions of 2,4,6-tri-t-butylphenoxyl (TBP) with cumene hydroperoxide (ROOH), cumylperoxyl radicals (RO,), and molecular oxygen in benzene solution have been investigated kinetically by the ESR method. The rate constant of the reaction TBP + ROOH -% TBPH + RO2 has been estimated in the temperature