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Reaction of dihalocarbenes with aryl and cyclopropyl derivatives of ethylene

โœ Scribed by O. M. Nefedov; R. N. Shafran; A. I. Ioffe

Book ID
112438530
Publisher
Springer
Year
1977
Tongue
English
Weight
384 KB
Volume
26
Category
Article
ISSN
1573-9171

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The Reaction of Dihalocarbenes with Quad
The Reaction of Dihalocarbenes with Quadricyclane
โœ Charles William Jefford; Jacques Roussilhe; Mihail Papadopoulos ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 797 KB

The action of dichlorocarbene, generated in excess by phase-transfer catalysis at 20", on quadricyclane 2 resulted in a 7% conversion to at least seven products. The major component (51 % relative yield) was 3,4-exo-dichlorobicyclo[3.2.1 ]octa-2,6-diene (12). Cl c 1 c1 c1 16 12