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Reaction of diazomethane with clerocidin. Preparation of new clerodane diterpenoid derivatives

โœ Scribed by J.P. Jacquet; D. Bouzard; P. Remuzon


Book ID
103398608
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
160 KB
Volume
34
Category
Article
ISSN
0040-4039

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Reaction of duroquinone with diazomethan
โœ W.C. Howell; M. Ktenas; J.M. MacDonald ๐Ÿ“‚ Article ๐Ÿ“… 1964 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 246 KB

It has been reported previously (1) that duroquinone, in contrast to many other p-quinones (2,3), reacts with diazomethane by direct addition at the carbonyl groups. We have reinvestigated this system and find that, in fact, the reaction proceeds bJ addition to the olefinic centres of the duroquinon