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Reaction of dianions of acyclic ?-enamino ketones with electrophiles. Part 2. Oxiranes: synthesis of ??- and ?-hydroxy-?-enamino ketones and of ?-tetrahydrofurylidene ketones

✍ Scribed by Bartoli, Giuseppe; Bosco, Marcella; Cimarelli, Cristina; Dalpozzo, Renato; Palmier, Gianni

Book ID
120068965
Publisher
Royal Society of Chemistry
Year
1992
Weight
869 KB
Volume
16
Category
Article
ISSN
1472-7781

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πŸ“œ SIMILAR VOLUMES

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Selective generation techniques of U' and y dlamons of p-enammo ketones allow an almost complete regmcontrol m the reaction with aldehydes and ketones for the synthesis of p'-and Ghydroxy-P-enammo ketones An Important role IS also &splayed by bulkmess of the substltuent at the nitrogen atom The reac

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Phosphorylated enaminones can be obtained by the reaction of enaminone dianions with diphenylphosphinoyl chloride. In most cases, the reaction gave a mixture of monosubstituted and disubstituted compounds. Disubstituted compounds show an interesting NMR spectrum. In fact, the methine proton appears

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