ChemInform Abstract: Reaction of Dianions of Acyclic β-Enamino Ketones with Electrophiles. Part 8. Synthesis of Trialkylsilylenaminones and α ′-Silylated β-Diketones.
✍ Scribed by G. BARTOLI; M. BOSCO; R. DALPOZZO; A. DE NINO; E. IANTORNO; A. TAGARELLI; G. PALMIERI
- Book ID
- 112039882
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Selective generation techniques of U' and y dlamons of p-enammo ketones allow an almost complete regmcontrol m the reaction with aldehydes and ketones for the synthesis of p'-and Ghydroxy-P-enammo ketones An Important role IS also &splayed by bulkmess of the substltuent at the nitrogen atom The reac
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Reaction of 1-Substituted 2,2-Difluorostyrene with Dianions of β-Enamino Ketones. -The title reaction provides monosubstituted products (III) and pyridinone derivatives (IV) in ratios depending on the type of the .